Direct solution of the Schrodinger equation for some muonic molecules

Citation
Ws. Bian et al., Direct solution of the Schrodinger equation for some muonic molecules, CHEM PHYS, 242(2), 1999, pp. 195-202
Citations number
30
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS
ISSN journal
03010104 → ACNP
Volume
242
Issue
2
Year of publication
1999
Pages
195 - 202
Database
ISI
SICI code
0301-0104(19990401)242:2<195:DSOTSE>2.0.ZU;2-#
Abstract
We use the hyperspherical harmonic method developed by us to directly solve the Schrodinger equation for some muonic molecules without recourse to the Born-Oppenheimer approximation. In our method, a kind of simplified potent ial harmonic representation derived by us is used, and analytic expressions for all matrix elements are obtained; the generalized Laguerre function ex pansion method is used in the solution of the coupled differential equation s. The practical calculations yield very good results for the energy. For e xample, we obtain a ground-state energy of - 0.055623 pau for pp mu, - 0.02 9884 dau for dd mu, and -0.020521 tau for tt mu, in good agreement with the exact values of -0.055676 pau, -0.029921 dau, and - 0.020553 tau. The calc ulated energy values for the first excited states of pp mu, dd mu, tt mu ar e also reported. It is shown that, the potential harmonic representation we used is simple and convenient, and the convergence of the basis functions is uniform and rather rapid. (C) 1999 Elsevier Science B.V. All rights rese rved.