F. Vitali et al., Formation temperatures of clays from the volcaniclastic series of Site 841ODP: an oxygen isotopic record of a paleothermal flux into the Tonga forearc, CONTR MIN P, 134(4), 1999, pp. 364-369
Oxygen isotopic compositions of clay minerals were determined on representa
tive samples of the volcano-sedimentary series from Site 841 ODP (Tonga for
earc). This isotopic study has demonstrated an abnormally high crystallisat
ion temperature of the clay minerals with respect to temperature expected i
n burial diagenesis. Formation temperatures obtained using delta(18)O reach
up to 200 degrees C in a Fe-chlorite-corrensite paragenesis found in the v
icinity of basaltic andesite sills intruded into the Miocene tuffs. The pal
eothermal flux resulting from the cooling of the sills has produced very lo
w grade contact metamorphism in the Miocene Tonga forearc deposits. The con
sequence of this was the formation of a large amount of hydrous silicates c
haracterised near the sills by a Fe-clays-analcime mineralogical associatio
n.