BICYCLO[3.3.1]NONANES AS SYNTHETIC INTERMEDIATES .20. ASYMMETRIC-SYNTHESIS OF THE INDOLIZIDINE ALKALOIDS MONOMORINE-I AND INDOLIZIDINE 223AB

Citation
T. Momose et al., BICYCLO[3.3.1]NONANES AS SYNTHETIC INTERMEDIATES .20. ASYMMETRIC-SYNTHESIS OF THE INDOLIZIDINE ALKALOIDS MONOMORINE-I AND INDOLIZIDINE 223AB, Journal of the Chemical Society. Perkin transactions. I, (9), 1997, pp. 1315-1321
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
0300922X
Issue
9
Year of publication
1997
Pages
1315 - 1321
Database
ISI
SICI code
0300-922X(1997):9<1315:BASI.A>2.0.ZU;2-1
Abstract
Total syntheses of the indolizidine alkaloids monomorine I and indoliz idine 223AB have been achieved by starting from the chiral cis-2,5-dis ubsubstituted pyrrolidine or cis-2,6-disubstituted piperidine obtained from the asymmetric cleavage of 8-azabicyclo[3.2.l]octan-3-one or 9-a zabicyclo[3.3.1]nonan-3-one at the 'fork head'.