A family of novel proton-conducting membranes (PCMs) has been prepared from
low-cost, thermally stable materials and has been preliminarily characteri
zed. These PCMs consist of electronic nonconductive nanosize ceramic powder
, polymer binder, and an acid. They have the appearance of plastic, good me
chanical properties, nanosize pores (typically smaller then 1.5-3 nm) fille
d with the acid, and room-temperature conductivity of up to 0.21 S cm(-1) (
twice that of Nafion). Their thickness ranges from 40 to 400 mu m. These PC
Ms are considered to be excellent and low-cost candidates for many electroc
hemical applications, including fuel cells, electrolyzers, supercapacitors,
sensors, and batteries. (C) 1998 The Electrochemical Society. S1099-0062(9
8)07-021-7. All rights reserved.