Jh. Merkin et al., CHEMICAL WAVE RESPONSES TO PERIODIC STIMULI IN VULNERABLE EXCITABLE MEDIA, Journal of the Chemical Society. Faraday transactions, 93(9), 1997, pp. 1741-1745
Citations number
23
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
A reaction-diffusion model of the Belousov-Zhabotinsky (BZ) reaction i
s studied in which an initial 'conditioning' wave (CW) propagates thro
ugh an excitable system and sets up a region of inhomogeneity in which
the system becomes spontaneously oscillatory. The subsequent oscillat
ions in the concentrations of the intermediate species within this reg
ion can act as potential initiation sources for subsequent wave struct
ures. The range of different responses is determined for a 1D configur
ation by numerical computation and the parameter combinations for the
different types are located. Depending on the length of this region an
d the frequency of the spontaneous oscillations, the system may develo
p: sustained counter-propagating wave pairs, waves that propagate only
in the opposite direction to the CW, waves that propagate only in the
same direction as the CW, waves that propagate in alternating directi
ons or no subsequent wave development despite the periodic initiation.
The relationship of these different responses to experimental reactio
n-diffusion structures reported recently is discussed and the role of
the inhibitory species and its spatial profile is revealed.