SOLID-PHASE EXTRACTION OF PHENOLS AND PESTICIDES IN WATER WITH A MODIFIED POLYMERIC RESIN

Citation
N. Masque et al., SOLID-PHASE EXTRACTION OF PHENOLS AND PESTICIDES IN WATER WITH A MODIFIED POLYMERIC RESIN, Analyst, 122(5), 1997, pp. 425-428
Citations number
26
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00032654
Volume
122
Issue
5
Year of publication
1997
Pages
425 - 428
Database
ISI
SICI code
0003-2654(1997)122:5<425:SEOPAP>2.0.ZU;2-V
Abstract
A comparative study of a chemically modified polymeric resin which has a benzoyl group and several commercial sorbents, such as PLRP-S, Envi -chrom P and LIChrolut EN, for the solid-phase extraction of various p henolic compounds and pesticides was carried out, Selectivity and brea kthrough volumes for these compounds with different sorbents were stud ied by coupling an on-line solid-phase extraction system with a modifi ed liquid chromatograph equipped with a UV detector, After determining the chromatographic conditions, linearity range and detection limits, the method was applied to the determination of these compounds in dri nking and surface mater, For 25 ml of sample, the recovery was >70% fo r all the compounds, except for 4-nitrophenol (62%), and detection lim its were between 0.2 and 0.8 mu g l(-1).