Mm. Heravi et al., Synthesis and characterization of novel heterocyclic system: 1,2,4-triazolo [3,4-b] 1,3-thiazin-4-ones, I J HET CHE, 8(3), 1999, pp. 245-246
The addition of dimethyl acetytenedicarboxylate to 3-thio-1,2,4-triazoles a
fforded in good yield cycloadducts which were characterized by IR, mass and
H-1 and (CNMR)-C-13 spectroscopy. On the basis of H-1 and C-13 chemical sh
ifts the products were identified as 6-substituted 2-methoxycarbonyl-1,2,4-
triazolo [3,4-b] 1,3-thiazin-4-ones(2).