We have measured the photoluminescence (PL) spectra of GaAs/GaInP single qu
antum wells at pressures up to similar to 5 GPa, and investigated the chara
cteristics of the 1.46 eV deep emission band. It has a very long decay time
of 200-400 ns. In addition, at normal pressure, unlike the emission from t
he GaAs well, a strong blueshift of the spectral position with excitation i
ntensity is observed. With increasing pressure, the deep emission shows a s
ublinear shift towards higher energy while the GaAs well exhibits a linear
shift. The pressure-dependent PL behavior at lower excitation intensity is
rather similar to those observed for partially ordered GaInP alloys. These
results suggest that the presence of ordered GaInP layers plays an importan
t role in the radiative recombination at 1.46 eV, and the 1.46 eV deep emis
sion is related to the interface transitions of electrons and holes localiz
ed at the heterointerface.