Model for the electrorheological effect in flowing polymeric nematics

Citation
Rf. Rodriguez et al., Model for the electrorheological effect in flowing polymeric nematics, J CHEM PHYS, 110(16), 1999, pp. 8197-8204
Citations number
21
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL PHYSICS
ISSN journal
00219606 → ACNP
Volume
110
Issue
16
Year of publication
1999
Pages
8197 - 8204
Database
ISI
SICI code
0021-9606(19990422)110:16<8197:MFTEEI>2.0.ZU;2-Z
Abstract
An analytical model to study the response of a polymeric nematic confined i n a rectangular cell, to a dc electric field is presented. The effect of a pressure-driven plane Poiseuille flow and its competition with the electric field is explicitly considered. For the final stationary state where the i nduced reorientation of the director has already occurred, an aligned struc ture with a greatly enhanced viscosity (electrorheological effect) is produ ced. For this same state the first normal stress difference is calculated a s a function of position and of the applied field. For this quantity, regio ns of negative and positive values develop along the direction of the veloc ity gradient and an increase in the electric field or the flow causes an au gmented effect in its profiles. The net force between the plates is also ca lculated. As the Reynolds number increases, it is found that it also change s sign from positive to negative, and the effect is more pronounced as the strength of the electric field increases. Finally, the paper is closed by d iscussing the scope and limitations of the model and methods employed. (C) 1999 American Institute of Physics. [S0021-9606(99)51416-5].