Six years of UARS Microwave Limb Sounder HNO3 observations: Seasonal, interhemispheric, and interannual variations in the lower stratosphere

We present an overview of the seasonal, interhemispheric, and interannual v ariations in the distribution of HNO3 in the lower stratosphere based on me asurements of gas-phase HNO3 made by the UARS Microwave Limb Sounder (MLS) through six complete annual cycles in both hemispheres, Outside of the wint er polar regions, zonal-mean HNO3 mixing ratios on the 465-K potential temp erature surface are comparable in the two hemispheres in all latitude bands and in all years examined. Except at high latitudes, interannual variabili ty is minimal, and there is no significant hemispheric asymmetry in the ove rall HNO3 distribution or its seasonal cycle. Although the Antarctic experi ences widespread severe denitrification, the MLS data indicate that the den itrification is not complete; that is, not all polar stratospheric cloud (P SC) particles sediment out of the lower stratosphere. Replenishment of HNO3 at 465 K during the mid- to late-winter period (when temperatures, though still low, are generally rising) is most likely achieved through a combinat ion of PSC evaporation and continuing weak diabatic descent. Despite large interhemispheric and interannual differences in the extent and duration of PSC activity and denitrification, HNO3 recovers to similar values at the en d of every winter in both the Arctic and the Antarctic. Zonal-mean HNO3 val ues for the two hemispheres are virtually indistinguishable for the latitud es equatorward of 65 degrees, even during the winter months, Thus the effec ts of severe denitrification are confined in both space and time to the reg ions poleward of 65 degrees S during the winter and early spring.