An apparently anomalous low-energy mode has been observed in AgBr close to
the melting point, T-m, by inelastic neutron scattering using the IN6 time-
of-flight spectrometer at ILL. Further measurements using the RITA triple-a
xis spectrometer at Ris phi National Laboratory show that in fact the "anom
alous" behaviour is an artefact produced by the time-of-flight technique, c
oupled with a rapid expansion of the lattice close to melting. The behaviou
r of the 200 Bragg peak intensity as T-m is approached and is shown to be c
onsistent with the proposal that a second-order transition to a fast ion co
nducting phase would occur at T-c = 705 K > T-m, = 701 K, but that melting
occurs first. The observed quasi-elastic scattering is in excellent agreeme
nt with that expected from the ionic conductivity on the basis of the Nerns
t-Einstein relation. (C) 1999 Elsevier Science B.V. All rights reserved.