Synthesis of polymer-bound Fischer chromium alkoxy and aminocarbene complexes

Authors
Maiorana, S Seneci, P Rossi, T Baldoli, C Ciraco, M de Magistris, E Licandro, E Papagni, A Provera, S
Citation
S. Maiorana et al., Synthesis of polymer-bound Fischer chromium alkoxy and aminocarbene complexes, TETRAHEDR L, 40(18), 1999, pp. 3635-3638
Citations number
19
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
18
Year of publication
1999
Pages
3635 - 3638
Database
ISI
SICI code
0040-4039(19990430)40:18<3635:SOPFCA>2.0.ZU;2-5
Abstract
A series of polymer-bound Fischer chromium alkoxy and amino carbene type I complexes were synthesized by the thermal exchange of a CO ligand in chromi um pentacarbonyl carbenes 2 with triphenyl phosphine resin 1. The supported alkoxycarbene 3a proved to be reactive towards primary amines, and afforde d the polymer-bound aminocarbenes 5. Type II aminocarbenes were also prepar ed by reacting polymer-supported aminoacids with alkoxycarbene 2a. (C) 1999 Elsevier Science Ltd. All rights reserved.