Reversal of stereochemistry in diethylzinc addition to aldehydes by a simple change of the backbone substituent in L-serine derived ligands

Authors
Sibi, MP Chen, JX Cook, GR
Citation
Mp. Sibi et al., Reversal of stereochemistry in diethylzinc addition to aldehydes by a simple change of the backbone substituent in L-serine derived ligands, TETRAHEDR L, 40(17), 1999, pp. 3301-3304
Citations number
30
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
17
Year of publication
1999
Pages
3301 - 3304
Database
ISI
SICI code
0040-4039(19990423)40:17<3301:ROSIDA>2.0.ZU;2-4
Abstract
A change in the backbone substituent from phenyl to butyl group in L-serine -derived ligands provides a simple way to prepare enantiomeric products in diethylzinc addition to aldehydes. (C) 1999 Elsevier Science Ltd. All right s reserved.