Participation of the chiral sulfinyl functionality in palladium-catalyzed asymmetric vinylcyclopropane-cyclopentene rearrangements

Authors
Hiroi, K Yoshida, Y Kaneko, Y
Citation
K. Hiroi et al., Participation of the chiral sulfinyl functionality in palladium-catalyzed asymmetric vinylcyclopropane-cyclopentene rearrangements, TETRAHEDR L, 40(17), 1999, pp. 3431-3434
Citations number
9
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
17
Year of publication
1999
Pages
3431 - 3434
Database
ISI
SICI code
0040-4039(19990423)40:17<3431:POTCSF>2.0.ZU;2-K
Abstract
Stereochemical studies on the palladium-catalyzed asymmetric 1,3-rearrangem ents of [4-chiral arylsulfinyl-1,3(E or Z)-butadienyl]cyclopropanes to chir al cyclopentenes are described. The plausible mechanism for the rationaliza tion of the stereochemical outcomes is proposed, (C) 1999 Elsevier Science Ltd. All rights reserved.