COMPLEXES OF 2-FLUOROBENZOATE AND 4-FLUOROBENZOATE ANIONS AND THE CORRESPONDING METHYL-ESTERS WITH BETA-CYCLODEXTRIN AND THE CONJUGATE ACIDS OF 6(A)-AMINO-6(A)-DEOXY-BETA-CYCLODEXTRIN AND )-AMINO-3(A)-DEOXY-(2(A)S,3(A)S)-BETA-CYCLODEXTRIN IN AQUEOUS-SOLUTION - A F-19 NUCLEAR-MAGNETIC-RESONANCE STUDY

Authors
EASTON CJ LINCOLN SF PAPAGEORGIOU J SCHLIEBS DM
Citation
Cj. Easton et al., COMPLEXES OF 2-FLUOROBENZOATE AND 4-FLUOROBENZOATE ANIONS AND THE CORRESPONDING METHYL-ESTERS WITH BETA-CYCLODEXTRIN AND THE CONJUGATE ACIDS OF 6(A)-AMINO-6(A)-DEOXY-BETA-CYCLODEXTRIN AND )-AMINO-3(A)-DEOXY-(2(A)S,3(A)S)-BETA-CYCLODEXTRIN IN AQUEOUS-SOLUTION - A F-19 NUCLEAR-MAGNETIC-RESONANCE STUDY, Journal of chemical research. Synopses, (10), 1995, pp. 381
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
10
Year of publication
1995
Database
ISI
SICI code
0308-2342(1995):10<381:CO2A4A>2.0.ZU;2-U
Abstract
A F-19 NMR spectroscopic study shows that inclusion complexes of beta- cyclodextrin with aromatic guests are more stable than those of the co njugate acids of 6(A)-amino-6(A)-deoxy-beta-cyclodextrin and -amino-3( A)-deoxy-(2(A)S,3(A)S)-beta-cyclodextrin, presumably as a result of th e effect of the protonated amino substituents of the latter impinging on the character of their hydrophobic cavities.