We present an observational and theoretical study of the ionization fractio
n in several massive cores located in regions that are currently forming st
ellar clusters. Maps of the emission from the J = 1-->0 transitions of (CO)
-O-18, DCO+, N2H+, and (HCO+)-C-13, as well as the J = 2-->1 and 3-->2 tran
sitions of CS, were obtained for each core. Core densities are determined v
ia a large velocity gradient analysis with values typically of similar to 1
0(5) cm(-3). With the use of observations to constrain variables in the che
mical calculations, we derive electron fractions for our overall sample of
five cores directly associated with star formation and two apparently starl
ess cores. The electron abundances are found to lie within a small range, -
6.9 < log(10) x(e) < -7.3, and are consistent with previous work. We find n
o difference in the amount of ionization fraction between cores with and wi
thout associated star formation activity, nor is any difference found in el
ectron abundances between the edge and center of the emission region. Thus
our models are in agreement with the standard picture of cosmic rays as the
primary source of ionization for molecular ions. With the addition of prev
iously determined electron abundances for low-mass cores, and even more mas
sive cores associated with O and B clusters, we systematically examine the
ionization fraction as a function of star formation activity. This analysis
demonstrates that the most massive sources stand out as having the lowest
electron abundances (x(e) < 10(-8)).