SYNTHESIS OF VINCA ALKALOIDS AND RELATED-COMPOUNDS .74. REACTION OF (+ 4,6,7,12,12-BETA-OCTAHYDROINDOLO[2,3-A]QUINOLIZINE WITH HYDRIDE AND N-NUCLEOPHILES/

Citation
G. Kalaus et al., SYNTHESIS OF VINCA ALKALOIDS AND RELATED-COMPOUNDS .74. REACTION OF (+ 4,6,7,12,12-BETA-OCTAHYDROINDOLO[2,3-A]QUINOLIZINE WITH HYDRIDE AND N-NUCLEOPHILES/, Journal of chemical research. Synopses, (10), 1995, pp. 382
Citations number
4
Categorie Soggetti
Chemistry
ISSN journal
03082342
Issue
10
Year of publication
1995
Database
ISI
SICI code
0308-2342(1995):10<382:SOVAAR>2.0.ZU;2-1
Abstract
Reaction of the title methanesulfonate ester 1b with sodium azide gave derivatives 4 and 5 and with lithium tetrahydroaluminate the dialkyl compound 7, while with primary amines, in addition to the expected pro ducts (8a-r), compounds 9k-m possessing an unexpected ring system are obtained.