Insertion of a metal-bound nitrogen atom into a disulfide (S-S) bond. Synthesis and characterisation of [(CoL2)-L-III]ClO4 [HL = di(2-pyridylthio)amine]

Authors
Nakayama, H Prout, K Hill, HAO Datta, D
Citation
H. Nakayama et al., Insertion of a metal-bound nitrogen atom into a disulfide (S-S) bond. Synthesis and characterisation of [(CoL2)-L-III]ClO4 [HL = di(2-pyridylthio)amine], CHEM COMMUN, (8), 1999, pp. 695-696
Citations number
14
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
8
Year of publication
1999
Pages
695 - 696
Database
ISI
SICI code
1359-7345(19990421):8<695:IOAMNA>2.0.ZU;2-6
Abstract
Reaction of Cis-[Co-III(NH3)(4)(H2O)(2)](ClO4)(3) With 2,2'-dithiodipyridin e (2,2'-DTDP) in nearly equimolar proportion generates [(CoL2)-L-III]ClO4 w here HL(H = dissociable proton) is di(2-pyridylthio)amine, resulting in an unprecedented insertion of a coordinated ammine N into the S-S bond of 2,2' -DTDP.