Syntheses of mixed-metal M2Ti2S4 cubane-type sulfido clusters (M = Ru, Rh,Ir, Cu) from a dinuclear organometallic thiotitanate anion

Authors
Amemiya, T Kuwata, S Hidai, M
Citation
T. Amemiya et al., Syntheses of mixed-metal M2Ti2S4 cubane-type sulfido clusters (M = Ru, Rh,Ir, Cu) from a dinuclear organometallic thiotitanate anion, CHEM COMMUN, (8), 1999, pp. 711-712
Citations number
25
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
8
Year of publication
1999
Pages
711 - 712
Database
ISI
SICI code
1359-7345(19990421):8<711:SOMMCS>2.0.ZU;2-5
Abstract
The dinuclear organometallic thiotitanate anion [(CpTiS)(2)(mu-S)(2)](2-) r eacted with [Cp*Ru(mu(3)-Cl)](4), [(cod)M(mu-Cl)](2) (M = Rh, Ir) and [Cu(m u(3)-Cl)(PPh3)](4) to afford the early-late heterobimetallic cubane-type su lfide clusters [(CpTi)(2)(Cp*Ru)(2)(mu(3)-S)(4)], [(CPTi)(2) {M(cod)}(2)(mu (3)-S)(4)] and [(CpTi)(2){Cu(PPh3)}(2)(mu(3)-S)(4)], respectively.