A simple route to multifunctional phosphide and amide donor sets; syntheses and structures of [{(BuPAs)-P-t(NMe2)(2)}K center dot pmdeta](2) and [{CyNAs(NMe2)(2)K}(2)](infinity)

Authors
Beswick, MA Bashall, A Hopkins, AD Kidd, SJ Lawson, YG McPartlin, M Raithby, PR Rothenberger, A Stalke, D Wright, DS
Citation
Ma. Beswick et al., A simple route to multifunctional phosphide and amide donor sets; syntheses and structures of [{(BuPAs)-P-t(NMe2)(2)}K center dot pmdeta](2) and [{CyNAs(NMe2)(2)K}(2)](infinity), CHEM COMMUN, (8), 1999, pp. 739-740
Citations number
24
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
8
Year of publication
1999
Pages
739 - 740
Database
ISI
SICI code
1359-7345(19990421):8<739:ASRTMP>2.0.ZU;2-7
Abstract
The syntheses of [(BuPAs)-P-t(NMe2)(2)K.pmedta](2) 1 and [{CyN-As(NMe2)(2)K }(2)](infinity) 2 from the reactions of [As(NMe2)(3)] with (BuPH2)-P-t and CyNH2, respectively, in the presence of potassiated bases exemplify a gener al approach to multifunctional secondary phosphide and amide anions contain ing variable sets of group 15 donor centres.