Ci. Butoi et al., Control of surface film composition and orientation with downstream PECVD of hexafluoropropylene oxide, CHEM MATER, 11(4), 1999, pp. 862
Highly oriented fluorocarbon films are deposited downstream from an inducti
vely coupled rf plasma using hexafluoropropylene oxide (HFPO). Angle-depend
ent XPS results [takeoff angles of 0 degrees (upper) and 80 degrees (lower)
] demonstrate that the films comprise CF2 chains terminated by CF3 groups a
t the outer surface of the film. NEXAFS data establishes that the CF2 group
s are aligned in chains which are oriented normal to the substrate.