In this paper a detailed experimental study of Coherent Population Trapping
(CPT) effect un sodium induced by a dye-laser operating in a three-mode re
gime is presented and a detailed analysis of the role of velocity changing
collisions is made. These collisions show a very small relaxation effect on
the dark resonances which are visible even at high pressures. For the firs
t time we demonstrate the persistence of the ground state coherence to pres
sures up to one atmosphere for a relatively "heavy" buffer gas like argon.
The experimental results have been compared with theory and a very good agr
eement has: been obtained. Preliminary results on the effect of Na-N-2 coll
isions on Coherent population Trapping are presented.