Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane) persulfate: A mild and efficient oxidant for cleavage of oxime double bonds under anhydrous conditions

Authors
Hajipour, R Mohammadpoor-Baltork, I Kianfar, G
Citation
R. Hajipour et al., Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane) persulfate: A mild and efficient oxidant for cleavage of oxime double bonds under anhydrous conditions, I J CHEM B, 38(2), 1999, pp. 221-224
Citations number
39
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY
ISSN journal
03764699 → ACNP
Volume
38
Issue
2
Year of publication
1999
Pages
221 - 224
Database
ISI
SICI code
0376-4699(199902)38:2<221:BPAMAE>2.0.ZU;2-Z
Abstract
Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane)persulfate (BAABCPS) 1 read ily prepared as orange solid from commercially available 1,4-diazabicyclo[2 .2.2]octane (DABCO) and potassium persulfate, converts oximes and alpha-sul finyl oximes to the corresponding carbonyl compounds and beta-keto sulfoxid es respectively, the yields and enantiomeric purity are excellent.