On the mechanism of four-coordinate aluminum alkyls interaction with dioxygen, evidence for spatial demands in the autoxidation reaction

Authors
Lewinski, J Zachara, J Kopec, T Madura, I Prowotorow, I
Citation
J. Lewinski et al., On the mechanism of four-coordinate aluminum alkyls interaction with dioxygen, evidence for spatial demands in the autoxidation reaction, INORG CH C, 2(4), 1999, pp. 131-134
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
2
Issue
4
Year of publication
1999
Pages
131 - 134
Database
ISI
SICI code
1387-7003(199904)2:4<131:OTMOFA>2.0.ZU;2-S
Abstract
The reactivity of four-coordinate dialkylaluminum derivatives of pyrazole t owards dioxygen, particularly with regard to the effect of steric hindrance s caused by the metal center bonded substituents and those resulting from t he ligand, has been investigated. Our preliminary results show that spatial demands play a vital role in the autoxidation of four-coordinate aluminum alkyls. (C) 1999 Elsevier Science S.A, All rights reserved.