Synthesis and structure of a disilver(I) complex of a thiophene-linked Schiff base azacryptand

Authors
Adams, H Elsegood, MRJ Fenton, DE Heath, SL Ryan, SJ
Citation
H. Adams et al., Synthesis and structure of a disilver(I) complex of a thiophene-linked Schiff base azacryptand, INORG CH C, 2(4), 1999, pp. 139-142
Citations number
8
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
2
Issue
4
Year of publication
1999
Pages
139 - 142
Database
ISI
SICI code
1387-7003(199904)2:4<139:SASOAD>2.0.ZU;2-Q
Abstract
The synthesis and crystal structure of a mixed anion disilver(I) complex of a thiophene-linked Schiff base azacryptand are reported. The crystalline s pecies is not stable at ambient temperature and the structure reveals a pos sible mechanism for the breakdown of the crystals. (C) 1999 Elsevier Scienc e S.A. All rights reserved.