Synthesis and X-ray characterization of the quindecanuclear nickel/sulfur paramagnetic cluster [Ni-15(mu(3)-S)(6)(mu(4)-S)(9)(PEt3)(6)](+)

Authors
Berti, E Cecconi, F Ghilardi, CA Midollini, S Orlandini, A
Citation
E. Berti et al., Synthesis and X-ray characterization of the quindecanuclear nickel/sulfur paramagnetic cluster [Ni-15(mu(3)-S)(6)(mu(4)-S)(9)(PEt3)(6)](+), INORG CH C, 2(4), 1999, pp. 146-148
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
2
Issue
4
Year of publication
1999
Pages
146 - 148
Database
ISI
SICI code
1387-7003(199904)2:4<146:SAXCOT>2.0.ZU;2-W
Abstract
The quindecanuclear nickel/sulfur cluster [Ni-15(mu(3)-S)(6)(mu(4)-S)(9)(PE t3)(6)](+) has been isolated by reaction of Ni(ClO4)(2). 6H(2)O with H2S an d PEt3 in ethanol/dichloromethane solution and has been characterized by X- ray diffraction studies. (C) 1999 Elsevier Science S.A. All rights reserved .