K. Oikawa et al., EFFECT OF TITANIUM ADDITION ON THE FORMATION AND DISTRIBUTION OF MNS INCLUSIONS IN STEEL DURING SOLIDIFICATION, ISIJ international, 37(4), 1997, pp. 332-338
Effect of titanium addition on the size and dispersion of MnS inclusio
ns in Fe-0.1C-1Mn-0.02S(mass%) base alloys has been investigated by mi
croscopy. Titanium addition brings about a marked decrease in the size
of MnS inclusions which are otherwise large and globular in Ti-free s
pecimens. The formation mechanism of MnS inclusions is discussed on th
e basis of phase diagram information and thermodynamics of particle en
gulfment during solidification. It is shown that the reduction in size
of the MnS particles consequent on Ti addition is directly the result
of successive nucleation events involving (Ti,Mn)O and MnS at the sol
id/liquid interface of iron.