At. Aguayo et al., Deactivation by coke of a catalyst based on a SAPO-34 in the transformation of methanol into olefins, J CHEM TECH, 74(4), 1999, pp. 315-321
When methanol is converted to olefins on a SAPO-34 catalyst between 350 and
425 degrees C, there is a rapid initial formation of coke, followed by a s
lower rate of coke deposition. The rate of coke formation decreases with in
creasing temperature, and with progression through the catalyst bed. The co
ke completely blocks the internal channels of the SAPO-34 crystals and subs
equently blocks the mesopores (intercrystalline and those of the bentonite)
. Coke deposition mainly blocks sites of acidic strength above 175 kJ mol(-
1). The presence of water in the feed lessens coke formation, either by con
verting Lewis to Bronsted sites or by competing for surface sites with coke
precursors. (C) 1999 Society of Chemical Industry.