W. Janusz, Determination of the ionization and complexation surface reaction constants in the metal oxide/electrolyte system, J DISP SCI, 20(3), 1999, pp. 1041-1067
The description of electrical double layer at the metal oxide/electrolyte i
nterface requires the determination of the constants of the ionization and
complexation of surface groups. These constants allows to determine distrib
ution of surface charge and a potential across the interface region. The di
fferent methods of the estimation of these constants at the metal oxide/ele
ctrolyte interface, including potentiometric titration, ion adsorption data
and zeta potential are compared.