Reactivity of antimony mixed halides for the fluorination of tetrachlorethene (PCE) in liquid phase

Authors
Brunet, S Batiot, C Moriceau, P Thybaud, N
Citation
S. Brunet et al., Reactivity of antimony mixed halides for the fluorination of tetrachlorethene (PCE) in liquid phase, J MOL CAT A, 142(2), 1999, pp. 183-186
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN journal
13811169 → ACNP
Volume
142
Issue
2
Year of publication
1999
Pages
183 - 186
Database
ISI
SICI code
1381-1169(19990610)142:2<183:ROAMHF>2.0.ZU;2-U
Abstract
The active species for the liquid phase fluorination of tetrachloroethene ( PCE) was produced by in situ reaction between HF and SbCl5. By comparison w ith various commercial antimony mixed halides (SbCl4F, SbC3F2, SbCl3F2 and SbClF4), the active species, produced in situ in our conditions, could be c omposed by SbCl4F or/and SbCl3F2 or a mixture of both. (C) 1999 Elsevier Sc ience B.V. All rights reserved.