HYDROTHERMAL SYNTHESIS, CRYSTAL-STRUCTURE AND PHOTOELECTRIC PROPERTIES OF KCUPO4-CENTER-DOT-6H(2)O

Authors
YANG GY CHAI XD ZHANG J XU JN WANG DJ XU JQ BU WM YE L YANG GD FAN YG
Citation
Gy. Yang et al., HYDROTHERMAL SYNTHESIS, CRYSTAL-STRUCTURE AND PHOTOELECTRIC PROPERTIES OF KCUPO4-CENTER-DOT-6H(2)O, Synthetic metals, 86(1-3), 1997, pp. 2267-2268
Citations number
6
Categorie Soggetti
Physics, Condensed Matter","Material Science","Polymer Sciences
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
86
Issue
1-3
Year of publication
1997
Pages
2267 - 2268
Database
ISI
SICI code
0379-6779(1997)86:1-3<2267:HSCAPP>2.0.ZU;2-H
Abstract
A new double salt of phosphoric acid, KCuPO4 . 6H(2)O, has been hydrot hermally synthesized. Its structure was determined and refined by full -matrix least-squares procedures using automatic diffractometer data t o a residual R=0.0628(R-W=0.2131). The space group is P2/c with a=6.13 03(3)Angstrom, b=12.1781(6)Angstrom, c=8.9962(2)Angstrom, beta=105.018 (4)degrees, V=648.68(6)Angstrom(3), and Z=2. The measurement of surfac e photovoltage as function of wavelength indicates that this new compo und can yield obvious photovoltaic response in 550-800 nm visible regi on and exhibit better photoelectric conversion efficiency.