Synthesis of 12-substituted 1-carba-closo-dodecaborate anions and first hyperpolarizability of the 12-C7H6+-CB11H11- ylide

Salts of 12-alkyl and 12-phenyl derivatives of the CB11H12- anion are prepa red in 50-60% yields from the 12-iodo-CB11H11- anion by Pd-catalyzed cross- coupling with Grignard reagents. The tropylium ylide 12-C7H6+-CB11H11- is m ade in 54% yield by reaction of C7H7+ With CB11H12- Its ground-state dipole moment is 11.25 +/- 0.1 D and its first hyperpolarizability is beta = 236 x 10(-30) esu at 1064 nm, as determined by hyper-Rayleigh scattering measur ement. This value is ten times that of p-nitroaniline and is surprisingly l arge considering that the compound is colorless.