In this paper we report the multinuclear NMR investigation of sodium N-dode
canoyl-L-prolinate (1), in CD3OD and in D2O, at various concentrations. Due
to the amide bond, this surfactant has two conformational isomers, l-E and
1-Z, and the ratio [1-E]/[1-Z] in micellized surfactant is different from
that in CD3OD or in D2O at [1] < cmc (ca. 0.5 and 1.5, respectively). Under
micellar aggregation conditions, the presence of the two isomers resulted
in two signals for most of the nuclei. Because this feature is not observed
under nonaggregating conditions, this indicates that the isomers micellize
on the basis of a different stereochemical code in conformational domains
that give two different H-1 and C-13 NMR spectra. Na-23 spin relaxation tim
e shows that the counterion is highly bonded to the aggregate.