Fullerene solids exhibit textbook examples of orientational freezing transi
tions, i.e. structural transitions from a high temperature phase, where the
molecules undergo rapid reorientation, to a low temperature phase where th
e molecules are locked-in into discrete orientations. In general, even low
temperature phases are not completely ordered because of frozen-in orientat
ional disorder, partly also because of a high density of stacking faults. D
iffuse scattering has been used extensively to characterize both dynamic an
d static disorder in fullerene solids. A review is given on the experimenta
l results as well as on the various techniques employed to analyze the data
.