The properties of GaAs oxides prepared by liquid phase chemical-enhanced ox
idation (LPCEO) technique are investigated. The refractive indices of the o
xide films appear to increase with oxidation time, and can be well controll
ed by the oxidation procedures. It has been found that the accumulation of
As compounds within the oxides is the origin for the phenomena. Based on th
e current-voltage (I-V) characteristics of the metal-oxide-semiconductor co
nductor (MOS) structures, the leakage current density of the oxide has been
demonstrated to be low (similar to 2 x 10(-8) A/cm(2)), and a high dielect
ric breakdown strength of similar to 8 MV/cm is achieved. Finally, the comp
lete chemical compositions from the oxide surface to the oxide-substrate in
terface has been determined by X-ray photoelectron spectroscopy (XPS) and s
econdary ion mass spectroscopy (SIMS) depth profiles.