Theory of nucleation and growth during phase separation

Authors
Citation
C. Sagui et M. Grant, Theory of nucleation and growth during phase separation, PHYS REV E, 59(4), 1999, pp. 4175-4187
Citations number
53
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW E
ISSN journal
1063651X → ACNP
Volume
59
Issue
4
Year of publication
1999
Pages
4175 - 4187
Database
ISI
SICI code
1063-651X(199904)59:4<4175:TONAGD>2.0.ZU;2-I
Abstract
We present a new model for the entire process of phase-separation that comb ines steady-state homogeneous nucleation theory with the classical Lifshitz -Slyozov mechanism of ripening, modified to account for the substantial cor relations among the droplets. A set of self-consistent interface equations describes the decay of metastable states, incorporating naturally the cross over from early-stage nucleation to the late-stage scaling regime without a d hoc assumptions. We present simulation results for both two and three dim ensions. We also present a mean-field, Thomas-Fermi approximation that prov ides an approximate solution to the many-body problem.