Radiation stability of colloidal metals in aqueous solutions

Citation
Bg. Ershov et al., Radiation stability of colloidal metals in aqueous solutions, RES CHEM IN, 25(3), 1999, pp. 299-312
Citations number
19
Categorie Soggetti
Chemistry
Journal title
RESEARCH ON CHEMICAL INTERMEDIATES
ISSN journal
09226168 → ACNP
Volume
25
Issue
3
Year of publication
1999
Pages
299 - 312
Database
ISI
SICI code
0922-6168(1999)25:3<299:RSOCMI>2.0.ZU;2-T
Abstract
The effect of ionizing radiation (accelerated electrons and gamma-rays of C o-60) on the stability of aqueous solutions of colloidal silver, cadmium, c obalt, thallium, copper and lead has been studied. The threshold of absorbe d dose, at which the stability of the colloid dramatically decreases and co agulation of silver, cadmium and cobalt occurs, was found. This critical do se corresponds to the reduction of metal ions that determines the electrica l potential of the sols. "Radiation" neutralization was not observed in the case of thallium, copper or lead. A mechanism of the effect of radiation, taking into account the electrostatic factor in the stability of metal sols is considered.