The dynamics of charge transfer processes of oxygen on metal surfaces are i
nvestigated. The analysis is based on a set of diabatic potential energy su
rfaces, each representing a different charged oxygen species. Empirical uni
versal potential energy functions have been constructed that mimic the oxyg
en-silver, oxygen-aluminum and oxygen-cesium systems. The differences betwe
en the work functions of these metals are reflected in the potential parame
ters. The dynamics are followed by solving the multichannel time-dependent
Schrodinger equation starting from oxygen in the gas phase. Only the direct
short time part of the dynamics is followed leading to the creation O-2(-)
in the gas phase as well as dissociative chemisorption. A large portion of
the wave function is trapped in molecular chemisorption charged states. It
is found that the position of the crossing seam between potentials has a p
rofound influence on the outcome. (C) 1999 Elsevier Science B.V. All rights
reserved.