Citation
Sj. Cantrill et al., A new protocol for rotaxane synthesis, TETRAHEDR L, 40(19), 1999, pp. 3669-3672
Citations number
37
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039
→ ACNP
Volume
40
Issue
19
Year of publication
1999
Pages
3669 - 3672
Database
ISI
SICI code
0040-4039(19990507)40:19<3669:ANPFRS>2.0.ZU;2-V
Abstract
A novel [2]rotaxane was synthesized when an aniline-bearing [2]pseudorotaxa
ne-generated by the hydrogen bond-driven threading of a dibenzylammonium fi
lament through the cavity of the macrocyclic polyether dibenzo[24]crown-8-w
as stoppered via reaction with a bulky isocyanate. Complete characterizatio
n of the [2]rotaxane was accomplished by NMR spectroscopy, mass spectrometr
y and X-ray crystallography. (C) 1999 Elsevier Science Ltd. All rights rese
rved.