Synthesis and rearrangement of (Z)-allylic trichloroacetimidates.

Authors
Martin, C Bortolussi, M Bloch, R
Citation
C. Martin et al., Synthesis and rearrangement of (Z)-allylic trichloroacetimidates., TETRAHEDR L, 40(19), 1999, pp. 3735-3736
Citations number
12
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
19
Year of publication
1999
Pages
3735 - 3736
Database
ISI
SICI code
0040-4039(19990507)40:19<3735:SARO(T>2.0.ZU;2-N
Abstract
An efficient synthesis of (Z)-allylic trichloroacetimidates starting from l actol 1 is described. Thermal [3,3] rearrangement of these imidates occurre d with excellent chirality transfer to give allylic amides. (C) 1999 Elsevi er Science Ltd. All rights reserved.