Zinc(II) complexes of bidentate Schiff base ligands containing methoxyphenyl and nitrophenyl groups

Authors
Tatar, L Ulku, D Atakol, O
Citation
L. Tatar et al., Zinc(II) complexes of bidentate Schiff base ligands containing methoxyphenyl and nitrophenyl groups, ACT CRYST C, 55, 1999, pp. 508-510
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
4
Pages
508 - 510
Database
ISI
SICI code
0108-2701(19990415)55:<508:ZCOBSB>2.0.ZU;2-7
Abstract
In the title compounds, bis[2-(3-nitrophenylnitrilomethylidyne)phenolato-N, O]zinc(II), [Zn(C13H9N2O3)(2)], and bis[2-(3-methoxyphenylnitrilomethylidyn e)phenolato-N,O]zinc(II), [Zn(C14H12NO2)(2)], the tricilinic unit cell cont ains two inversion-related molecules, In both compounds, the Zn atom is in a slightly distorted tetrahedral coordination involving O and N atoms of tw o bidentate ligands, The dihedral angle defined by the two chelate rings is 98.09(4)degrees for the methoxyphenyl complex and 98.05(7)degrees for the nitrophenyl complex. The molecules are crosslinked via intermolecular hydro gen bonds.