Diaquabis(pyridazin-1-ium-3,6-dicarboxyl-ato-N-2,O-3)copper(II) dihydrate

Citation
S. Sobanska et al., Diaquabis(pyridazin-1-ium-3,6-dicarboxyl-ato-N-2,O-3)copper(II) dihydrate, ACT CRYST C, 55, 1999, pp. 553-555
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
4
Pages
553 - 555
Database
ISI
SICI code
0108-2701(19990415)55:<553:DD>2.0.ZU;2-N
Abstract
The crystal structure of the title compound, [Cu(C6H3-N2O4)(2)(H2O)(2)]. 2H (2)O, shows it to exist as a monometalic and centrosymmetric complex with o ctahedral coordination of copper to each of two pyridazinium-3,6-dicarboxyl ate groups lying in the equatorial plane via one N and one O atom, and to t wo water molecules in trans-diaxial positions. Two additional water molecul es are included in the cell. A network of hydrogen bonding links the carbox yl groups and the water molecules of the cell.