2-aminopyrimidine-fumaric acid cocrystal

Authors
Goswami, S Mahapatra, AK Nigam, GD Chinnakali, K Fun, HK Razak, IA
Citation
S. Goswami et al., 2-aminopyrimidine-fumaric acid cocrystal, ACT CRYST C, 55, 1999, pp. 583-585
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
4
Pages
583 - 585
Database
ISI
SICI code
0108-2701(19990415)55:<583:2AC>2.0.ZU;2-9
Abstract
In crystals of the title compound, 2-aminopyrimidin-1-ium hemifumarate hemi fumaric acid, C4H6N3+. 0.5C(4)H(2)O(4)(2-). 05C(4)H(4)O(4), the asymmetric unit contains one 2-aminopyrimidine cation, C4H6N3+, protonated at a pyrimi dine ring-N atom, one half-molecule of fumaric acid, C4H4O4, and one half o f a fumarate ion, C4H2O42-. These are linked by N-H ... O, O-H ... O and re latively strong C-H ... O bonds, resulting in eight- and nine-membered hydr ogen-bonded rings and an extended supramolecular structure.