The transesterification of 0.5 M divinyladipate with 0.25 M arabinose in di
methylformamide for 7 days was catalyzed by Streptomyces sp. alkaline prote
ase to give 5-O-vinyladipoyl-D-arabinofuranose at ca. 50% yield. Only enzym
atic transesterification of primary hydroxyl group of arabinofuranose proce
eded without esterification of arabinopyranose.