Chemical interconversions of 4-cyanophenyl 1,5-dithio-beta-D-xylopyranoside (Beciparcil (R)): structural modification at the C-4 position

Citation
Y. Li et al., Chemical interconversions of 4-cyanophenyl 1,5-dithio-beta-D-xylopyranoside (Beciparcil (R)): structural modification at the C-4 position, CARBOHY RES, 314(3-4), 1998, pp. 161-167
Citations number
20
Categorie Soggetti
Agricultural Chemistry","Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
CARBOHYDRATE RESEARCH
ISSN journal
00086215 → ACNP
Volume
314
Issue
3-4
Year of publication
1998
Pages
161 - 167
Database
ISI
SICI code
0008-6215(199812)314:3-4<161:CIO41>2.0.ZU;2-B
Abstract
The title dithioxyloside 1, an orally active antithrombotic agent, as its 2 ,3-isopropylidene acetal, was converted into the corresponding glycos-4-ulo se, which served as precursor via reduction to the 4-epimer of 1 and via ox imation-reduction to the 4-acetamido-4-deoxy 4-epimer of 1. (C) 1998 Elsevi er Science Ltd. All rights reserved.