Reactivity of substituted 3-(diethylphosphonyl)-1-(trialkylsilyl)alka-1,3-dienes: Regioselective epoxidation and cyclopropanation reactions

Authors
Chevalier, F Al-Badri, H Collignon, N
Citation
F. Chevalier et al., Reactivity of substituted 3-(diethylphosphonyl)-1-(trialkylsilyl)alka-1,3-dienes: Regioselective epoxidation and cyclopropanation reactions, HETEROAT CH, 10(3), 1999, pp. 231-236
Citations number
25
Categorie Soggetti
Chemistry
Journal title
HETEROATOM CHEMISTRY
ISSN journal
10427163 → ACNP
Volume
10
Issue
3
Year of publication
1999
Pages
231 - 236
Database
ISI
SICI code
1042-7163(1999)10:3<231:ROS3>2.0.ZU;2-F
Abstract
When created with electrophilic mCPBA reagent, dienes I were efficiently ep oxidized at the silylated 1,2-double bond exclusively. Otherwise, regiosele ctive cyclopropanation of the phosphonylated 3,4-double bond was achieved b y using the nucleophilic Corey's reagent. (C) 1999 John Wiley & Sons, Inc.