Structural changes in 1,2 lambda(5)-azaphosphole/nitrilimine cycloaddition

Authors
Polborn, K Schmidpeter, A
Citation
K. Polborn et A. Schmidpeter, Structural changes in 1,2 lambda(5)-azaphosphole/nitrilimine cycloaddition, HETEROAT CH, 10(3), 1999, pp. 243-245
Citations number
2
Categorie Soggetti
Chemistry
Journal title
HETEROATOM CHEMISTRY
ISSN journal
10427163 → ACNP
Volume
10
Issue
3
Year of publication
1999
Pages
243 - 245
Database
ISI
SICI code
1042-7163(1999)10:3<243:SCI1LC>2.0.ZU;2-4
Abstract
Diphenylnitrilimine adds to the phosphazene bovid of the azaphosphole 1. A single-crystal X-ray investigation of the cycloadduct 3 shows a planar bicy clo[3.3.0]octane skeleton meridional to the trigonal bipyramidal phosphorus . The structural data are compared to those of the starting compound 1, to those of the trifluoroacetone adduct 2, and to the change from ideal tetrah edral to ideal tbp geometry. (C) 1999 John Wiley & Sons, Inc.