Total synthesis of (S)-(+)-melodorinol and (S)-(+)-acetylmelodorinol

Citation
M. Pohmakotr et al., Total synthesis of (S)-(+)-melodorinol and (S)-(+)-acetylmelodorinol, HETEROCYCLE, 51(4), 1999, pp. 795-802
Citations number
10
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
HETEROCYCLES
ISSN journal
03855414 → ACNP
Volume
51
Issue
4
Year of publication
1999
Pages
795 - 802
Database
ISI
SICI code
0385-5414(19990401)51:4<795:TSO(A(>2.0.ZU;2-O
Abstract
(S)-(+)-Melodorinol and (S)-(+)-acetylmelodorinol have been synthesized by reacting the lithiated butenolide with 2,3-O-alkylidene-D-glyceraldehyde fo llowed by successive elimination, hydrolysis, benzoylation and acetylation reactions.