Kinetics of the complexation of Ni(II) and Co(II) with L-2,6-diaminocaproic acid

Authors
Malhotra, HC Rattan, S Singh, V
Citation
Hc. Malhotra et al., Kinetics of the complexation of Ni(II) and Co(II) with L-2,6-diaminocaproic acid, I J CHEM A, 38(2), 1999, pp. 136-140
Citations number
16
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
38
Issue
2
Year of publication
1999
Pages
136 - 140
Database
ISI
SICI code
0376-4710(199902)38:2<136:KOTCON>2.0.ZU;2-O
Abstract
Kinetics of complexation of Ni(II) and Co(II) by L-2,6-diaminocaproic acid has been investigated as a function of pH and temperature at 0.1 M KNO3 usi ng stopped flow technique. The overall rate constants have been resolved in to stepwise rate constants. The activation parameters corresponding to each step have been evaluated. A reaction scheme on the basis of the comprehens ive kinetic study consistent with our kinetic data has been proposed.