Geometrical preferences in bis(dithiocarbamato)tin(IV) complexes: X-ray structure of cis-I2Sn[S2CN(C2H5)(2)](2) and theoretical investigations

Authors
Selvaraju, R Manoharan, M Laavanya, P Panchanatheswaran, K Venuvanalingam, P
Citation
R. Selvaraju et al., Geometrical preferences in bis(dithiocarbamato)tin(IV) complexes: X-ray structure of cis-I2Sn[S2CN(C2H5)(2)](2) and theoretical investigations, J CHEM R-S, (2), 1999, pp. 82-83A
Citations number
40
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF CHEMICAL RESEARCH-S
ISSN journal
03082342 → ACNP
Issue
2
Year of publication
1999
Pages
82 - 83A
Database
ISI
SICI code
0308-2342(199902):2<82:GPIBCX>2.0.ZU;2-T
Abstract
The geometry of Cis-l(2)Sn[S2CN(C2H5)(2)](2) is confirmed by single crystal X-ray analysis; the spectral data of the complex resemble those of the bro mo complex and PM3 calculations on octahedral complexes of the type XYSn[S2 CN(C2H5)(2)](2) reveal that their geometrical preferences depend upon the e lectron availability on the monodentate ligands X or Y.